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url url url url
  2. Weltenzyklopädie
  3. ثابت تفکیک - ویکی‌پدیا، دانشنامهٔ آزاد
ثابت تفکیک - ویکی‌پدیا، دانشنامهٔ آزاد
از ویکی‌پدیا، دانشنامهٔ آزاد

ثابت تفکیک در شیمی، زیست‌شیمی و داروشناسی نوع خاصی از ثابت تعادل است که تمایل یک مادهٔ بزرگتر را برای تفکیک برگشت‌پذیر به مواد کوچکتر اندازه‌گیری می‌کند مانند زمانی که یک کمپلکس به مولکول‌های سازنده‌اش تقسیم می‌شود یا یک نمک به یون‌های سازنده‌اش تجزیه می‌شود. ثابت تفکیک معمولاً با علامت مشخص می‌شود و وارون ثابت تشکیل است. در مورد یون‌های ثابت تفکیک را ثابت یونیزاسیون نیز می‌نامند.

برای یک واکنش عمومی

که در آن به و تجزیه می‌شود. ثابت تفکیک به صورت زیر تعریف می‌شود.[۱][۲]

که در آن [A]، [B] و [AxBy] هر یک غلظت‌های A، B و کمپلکس AxBy هستند.

منابع

  1. ↑ Zhou HX, Rivas G, Minton AP (2008). "Macromolecular crowding and confinement: biochemical, biophysical, and potential physiological consequences". Annu Rev Biophys. 37: 375–97. doi:10.1146/annurev.biophys.37.032807.125817. PMC 2826134. PMID 18573087.
  2. ↑ Minton AP (April 2001). "The influence of macromolecular crowding and macromolecular confinement on biochemical reactions in physiological media". J. Biol. Chem. 276 (14): 10577–80. doi:10.1074/jbc.R100005200. PMID 11279227.
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