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url url url url
  2. Weltenzyklopädie
  3. واکنش بوشوالد–هارت‌ویگ - ویکی‌پدیا، دانشنامهٔ آزاد
واکنش بوشوالد–هارت‌ویگ - ویکی‌پدیا، دانشنامهٔ آزاد
از ویکی‌پدیا، دانشنامهٔ آزاد
واکنش بوشوالد–هارت‌ویگ
نامگذاری شده پس از استفان ال. بوشوالد
جان اف. هارتویگ
نوع واکنش واکنش‌های جفت‌شدن
شناسه‌ها
در درگاه شیمی آلی buchwald-hartwig-reaction
RSC ontology ID RXNO:0000192

واکنش بوشوالد–هارت‌ویگ(به انگلیسی: Buchwald–Hartwig reaction) یا آمین‌دار کردن بوشوالد–هارت‌ویگ(به انگلیسی: Buchwald–Hartwig amination) گونه‌ای واکنش جفت شدن است که منجر به تشکیل یک پیوند کربن-نیتروژن می‌شود. این نام واکنش آلی از واکنش یک آریل هالید و یک آمین در حضور کاتالیزور پالادیم در محیط بازی تشکیل شده است.[۱]

واکنش بوچوالد–هارت‌ویگ
واکنش بوچوالد–هارت‌ویگ

سازوکار واکنش

سازوکار واکنش بوچوالد–هارت‌ویگ در حضور کاتالیزور به صورت زیر است:[۲][۳][۴][۵]

سازوکار چرخشی واکنش بوچوالد–هارت‌ویگ
سازوکار چرخشی واکنش بوچوالد–هارت‌ویگ

منابع

  1. ↑ http://www.name-reaction.com/buchwald-hartwig-amination
  2. ↑ Driver, M.S.; Hartwig, J.F. (1997), "Carbon−Nitrogen-Bond-Forming Reductive Elimination of Arylamines from Palladium(II) Phosphine Complexes", J. Am. Chem. Soc., 119 (35): 8232–8245, doi:10.1021/ja971057x{{citation}}: نگهداری یادکرد:نام‌های متعدد:فهرست نویسندگان (link)
  3. ↑ Hartwig, J.F.; Richards, S.; Barañano, D.; Paul, F. (1996), "Influences on the Relative Rates for C−N Bond-Forming Reductive Elimination and β-Hydrogen Elimination of Amides. A Case Study on the Origins of Competing Reduction in the Palladium-Catalyzed Amination of Aryl Halides", J. Am. Chem. Soc., 118 (15): 3626–3633, doi:10.1021/ja954121o{{citation}}: نگهداری یادکرد:نام‌های متعدد:فهرست نویسندگان (link)
  4. ↑ Driver, M.S.; Hartwig, J.F. (1995), "A Rare, Low-Valent Alkylamido Complex, a Diphenylamido Complex, and Their Reductive Elimination of Amines by Three-Coordinate Intermediates", J. Am. Chem. Soc., 117 (16): 4708–4709, doi:10.1021/ja00121a030{{citation}}: نگهداری یادکرد:نام‌های متعدد:فهرست نویسندگان (link)
  5. ↑ Widenhoefer, R.A.; Buchwald, S.L. (1996), "Halide and Amine Influence in the Equilibrium Formation of Palladium Tris(o-tolyl)phosphine Mono(amine) Complexes from Palladium Aryl Halide Dimers", Organometallics, 15 (12): 2755–2763, doi:10.1021/om9509608{{citation}}: نگهداری یادکرد:نام‌های متعدد:فهرست نویسندگان (link)

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